stllogo

Martes, Agosto 2, 2011

Entropy


Entropy is a thermodynamic property that can be used to determine the energy available for useful work in a thermodynamic process, such as in energy conversion devices, engines, or machines. Such devices can only be driven by convertible energy, and have a theoretical maximum efficiency when converting energy to work. During this work, entropy accumulates in the system, but has to be removed by dissipation in the form of waste heat.
In classical thermodynamics, the concept of entropy is defined phenomenologically by the second law of thermodynamics, which states that the entropy of an isolated system always increases or remains constant. Thus, entropy is also a measure of the tendency of a process, such as a chemical reaction, to be entropically favored, or to proceed in a particular direction. It determines that thermal energy always flows spontaneously from regions of higher temperature to regions of lower temperature, in the form of heat. These processes reduce the state of order of the initial systems, and therefore entropy is an expression of disorder or randomness. This picture is the basis of the modern microscopic interpretation of entropy in statistical mechanics. Here one defines entropy as the amount of information needed to specify the exact physical state of a system, given its thermodynamic specification. The second law is then a consequence of this definition and the fundamental postulate of statistical mechanics.
Thermodynamic entropy has the dimension of energy divided by temperature, and a unit of joules per kelvin (J/K) in the International System of Units.
The term entropy was coined in 1865 by Rudolf Clausius based on the Greek εντροπία [entropía], a turning toward, from εν- [en-] (in) and τροπή [tropē] (turn, conversion).[2][note 2]

Walang komento:

Mag-post ng isang Komento